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导师介绍

导师照片

赵延川

博士

研究员，博士生导师

中国科学院上海有机化学所

中国科学院氟化学重点实验室

联系电话：021-54925545

电子邮箱：zhaoyanchuan@sioc.ac.cn

联系地址：上海市徐汇区零陵路345号，君谋楼1401，邮编200032

学历及研究经历

Resume

2003.09 – 2007.07 吉林大学，学士

2007.09 – 2012.07 中国科学院上海有机化学研究所，博士 (导师：胡金波研究员)

2012.07 – 2013.03 中国科学院上海有机化学研究所，研究助理

2015.04 – 2015.05 美国伊利诺伊香槟分校，访问学者 (导师: Prof. Jeffrey S. Moore)

2013.03 – 2017.02 美国麻省理工学院，博士后 (导师: Prof. Timothy M. Swager)

2017.02 至今中国科学院上海有机化学研究氟化学重点实验室，研究员

代表工作：

1. Zhao, Y.; Rocha, S. V.; Swager, T. M. Mechanochemical Synthesis of Extended Iptycenes. J. Am. Chem. Soc. 2016, 138, 13834-13837.

2. Zhao, Y.; Chen, L.; Swager, T. M. Simultaneous Identification of Neutral and Anionic Species in Complex Mixtures without Separation. Angew. Chem., Int. Ed. 2016, 55, 917-921.

3. Zhao, Y.; Jiang, F.; Hu, J. Spontaneous Resolution of Julia-Kocienski Intermediates Facilitates Phase Separation to Produce Z- and E-Monofluoroalkenes. J. Am. Chem. Soc. 2015, 137. 5199-5203. Highlighted in JACS Spotlights and Chem-Station

4. Zhao, Y.; Swager, T. M. Simultaneous Chirality Sensing of Multiple Amines by ¹⁹F NMR. J. Am. Chem. Soc. 2015, 137, 3221-3224. Highlighted in C&E News, JACS Spotlights, Chemistry Views, and Chem-Station

5. Zhao, Y.; Markopoulos, G.; Swager, T. M. ¹⁹F NMR Fingerprints: Identification of Neutral Organic Compounds in a Molecular Container. J. Am. Chem. Soc. 2014, 136, 10683-10690. Highlighted in “In the Pipeline”

6. Zhao, Y.; Swager, T. M. Detection and Differentiation of Neutral Organic Compound by 19F NMR with a Tungsten Calix[4]arene Imido Complex. J. Am. Chem. Soc. 2013, 135, 18770-18773.

7. Zhao, Y.; Ni, C.; Jiang, F.; Gao, B.; Shen, X.; Hu, J. Copper-Catalyzed Debenzoylative Monofluoromethylation of Aryl Iodides Assisted by the Removable (2-Pyridyl)sulfonyl Group. ACS Catal. 2013, 3, 631-634.

8. Zhao, Y.; Gao, B.; Ni, C.; Hu, J. Copper-Mediated Fluoroalkylation of Aryl Iodides Enables Facile Access to Diverse Fluorinated Compounds: The Important Role of the (2-Pyridyl)sulfonyl Group. Org. Lett. 2012, 14, 6080-6083. Highlighted in Synfacts

9. Zhao, Y.; Bing, G.; Hu, J. From Olefination to Alkylation: In-Situ Halogenation of Julia-Kocienski Intermediates Leading to Formal Nucleophilic Iodo- and bromodifluoromethylation of Carbonyl Compounds. J. Am. Chem. Soc. 2012, 134, 5790-5793.

10. Zhao, Y.; Hu, J., Palladium-Catalyzed 2,2,2-Trifluoroethylation of Organoboronic Acids and Esters. Angew. Chem., Int. Ed. 2012, 51, 1033-1036.

11. Zhao, Y.; Huang, W.; Zheng, J.; Hu, J., Efficient and Direct Nucleophilic Difluoromethylation of Carbonyl Compounds and Imines with Me₃SiCF₂H at Ambient or Low Temperature. Org. Lett. 2011, 13, 5342-5345. Highlighted in Synfacts Me₃SiCF₂H is now commercially available at Sigma-Aldrich http://www.sigmaaldrich.com/catalog/papers/21910464

12. Zhao, Y.; Huang, W.; Zhu, L.; Hu, J., Difluoromethyl 2-Pyridyl Sulfone: A New gem-Difluoroolefination Reagent for Aldehydes and Ketones. Org. Lett. 2010, 12, 1444-1447. Difluoromethyl 2-Pyridyl Sulfone is now commercially available at Sigma-Aldrich http://www.sigmaaldrich.com/catalog/papers/20210302